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山本嘉则

 

山本嘉则:大连理工大学精细化工国家重点实验室,教授,外籍学术委员会委员。主要从事过渡金属催化的有机合成反应、天然产物的合成及有机光电材料的合成等研究,发表英文学术论文600多篇,著(编)书70多部,授权日本、美国和欧洲专利40多项。
1. 受教育经历
1970/08-1972/08 美国Purdue大学,博士后研究员
1965/04-1970/03 日本大阪大学大学院基础工学研究科,研究生/博士
1961/04-1965/03 日本大阪大学基础工学部合成化学科,本科/学士
2. 研究工作经历
2012/04-现在 大连理工大学,全勤教授
2010/01-2012/03 大连理工大学,特聘教授
1995/04-2012/03 日本东北大学大学院理学研究科,教授
1986/01-1995/03 日本东北大学理学部,教授
1977/01-1985/12 日本京都大学理学部,副教授 
1970/04-1976/12 日本大阪大学基础工学部,助手 
3. 曾任主要职务
2007/10-2012/03 日本东北大学原子分子材料科学高等研究所 所长
2006/04-2008/03 日本东北大学研究教育基础技术中心 主任
2006/04-2007/03 日本东北大学 副校长
2006/04-2007/03 日本化学会 副会长
2004/04-2006/03 日本东北大学理学研究科巨大分子解析研究中心 主任
2003/04-2004/03 日本东北大学理学研究科化学仪器分析中心 主任
2002/04-2006/03 日本文部科学省资助特别推进研究重大项目「使用Lewis酸?过渡金属催化剂开发环境友好型分子变换方法」首席科学家
2001/10-2006/03 日本文部科学省资助21世纪国家重大项目(COE项目)
「大分子复杂体系未踏化学」首席科学家
1999/01-2001/01 国际杂环化学学会 会长 
1997/04-2002/03 日本学术振兴会资助开拓未来学术研究重大项目 
「高效、原子经济有机合成与材料」首席科学家 
1997/04-2002/03 日本九州大学有机化学基础研究中心 兼职教授
1996/04-2003/03 日本东北大学多元物质科学研究所 兼职教授 
1995/10-2012/01  国际学术刊物Tetrahedron Publications编委
1995/10-2012/01 国际学术刊物Tetrahedron Letters 地区编辑
4. 主要获奖情况
2009年 英国王立化学会奖
2007年 美国化学会奖
2006年 紫绶褒章(日本政府奖,奖励在科学研究领域作出突出贡献者)
2002年 Humboldt研究奖(德国) 
1996年 日本化学会奖
1976年 日本化学会进步奖 
5. 科研成果(近5年来已发表的主要学术论文)
[1] S. Lu, T. Jin*, E. Kwon, M. Bao, Y. Yamamoto*, Highly Efficient Cu(OAc)2-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single-Bonded [60]Fullerene Dimers, Angew. Chem. Int. Ed. 51(3), 802–806, 2012.
[2] M. Yan, T. Jin*, Y. Ishikawa, T. Minato, T. Fujita, L. Chen, M. Bao, N. Asao, M. Chen, Y. Yamamoto, Nanoporous Gold Catalyst for Highly Selective Semihydrogenation of Alkynes: Remarkable Effect of Amine Additives, J. Am. Chem. Soc. 134(42), 17536–17542, 2012.
[3] T. Fujita*, P. Guan, K. McKenna, X. Lang, A. Hirata, L. Zhang, T. Tokunaga, S. Arai, Y. Yamamoto, N. Tanaka, Y. Ishikawa, N. Asao, Y. Yamamoto, J. Erlebacher, M. Chen*, Atomic Origins of the High Catalytic Activity of Nanoporous Gold, Nature Materials 11(9), 775–780, 2012.
[4] N. Asao*, N. Hatakeyama, Menggenbateer, T. Minato, E. Ito, M. Hara, Y. Kim, Y. Yamamoto*, M. Chen, W. Zhang, et al. Aerobic Oxidation of Alcohols in the Liquid Phase with Nanoporous Gold Catalysts, Chem. Commun. 48(38), 4540–4542, 2012.
[5] Y. Yamamoto, Interview with Yoshinori Yamamoto, Chem. Commun. 48(38), 4525–4526, 2012.
[6] X. Feng*, Y. Qu, Y. Han, X. Yu, M. Bao*, Y. Yamamoto, Copper-catalyzed Conversion of Aryl and Heteroaryl Bromides into the Corresponding Chloride, Chem. Commun. 48(76), 9468–9470, 2012. 
[7] T. Jin*, M. Yan, Y. Yamamoto*, Click Chemistry of Alkyne-Azide Cycloaddition Using Nanostructured Copper Catalysts, Chem. Cat. Chem. 4(9), 1217–1229, 2012.
[8] M. Akhtaruzzaman*, Y. Seya, N. Asao, A. Islam*, E. Kwon, A. El-ShafeiL. Han, Y. Yamamoto*, Donor-Acceptor Dyes Incorporating A Stable Dibenzosilole π-Conjugated Spacer for Dye-Sensitized Solar Cells, J. Mater. Chem. 22(21), 10771–10778, 2012.
[9] F. Yang, M. Akhtaruzzaman*, A. Islam, T. Jin*, A. El-Shafei*, C. Qin, L. Han, K. Alamry, S. Kosa, M. Husseine, A. Asiri, Y. Yamamoto, Structure-property Relationship of Naphthalene Based Donor-?-acceptor Organic Dyes for Dye-sensitized Solar Cells: Remarkable Improvement of Open-circuit Photovoltage, J. Mater. Chem. 22(42), 22550–22557, 2012.
[10] N. Asao, T. Jin, S. Tanaka, Y. Yamamoto, Molecular Catalysts to Nanostructured Materials Skeleton Catalysts, Pure and Applied Chemistry 84(8), 1771–1784, 2012.
[11] S. Lu, T. Jin*, M. Bao, Y. Yamamoto, NaOH-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes: Transition-Metal-Free, General, and Efficient Synthesis of Single-Bonded [60]Fullerene Dimers, Org. Lett. 14(13), 3466–3469, 2012. 
[12] F. Yang, T. Jin*, Y. Yamamoto*, Synthesis of 2,3-Dihydro-1H-inden-1-one Derivatives Via Ni-Catalyzed Intramolecular Hydroacylation, Tetrahedron 68(26), 5223–5228, 2012.
[13] G. Ferrara, T. Jin*, M. Akhtaruzzaman, A Islam, L. Han, H Jiang, Y. Yamamoto*, Cascade Cyclization of Aryldiynes Using Iodine: Synthesis of Iodo-Substituted Benzo[b]naphtho[2,1-d]thiophene Derivatives for Dye-Sensitized Solar Cells, Tetrahedron Lett. 53(15), 1946–1950, 2012.
[14] Y. Kawase, T. Yamagishi, T. Kutsuma, Z. Huo, Y. Yamamoto, T. Kimura, T. Nakata, T. Yokomatsu*, A Safe and Scalable Procedure for Preparation of α-Picoline-Borane from Sodium Mono-acyloxyborohydrides and α-Picoline, Org. Process Res. Dev. 16(3), 495–498, 2012.
[15] N. Asao*, Menggenbateer, Y. Seya, Y. Yamamoto*, M. Chen, W. Zhang, A. Inoue, Nanoporous Gold-Catalyzed [4 + 2] Benzannulation Between Ortho-Alkynylbenzaldehydes and Alkynes, Synlett. 23, 66–69, 2012.
[16] S. Lu, T. Jin*, M. Bao, A. Asiri, Y. Yamamoto*, Palladium-Catalyzed Bisfunctionalization of Active Alkenes by β-Acetonitrile-α-allyl Addition: Application to the Synthesis of Unsymmetric 1,4-Di(organo)fullerene Derivatives, Tetrahedron Lett. 53(10), 1210–1213, 2012.
[17] G. Ferrara, T. Jin*, K. Oniwa, J. Zhao, A. Asiri, Y. Yamamoto*, Synthesis of New Donor-Acceptor-Donor Materials via Au-Catalyzed Double Cascade Cyclization, Tetrahedron Lett. 53(8), 914–918, 2012. 
[18] S. Lu, T. Jin*, M. Bao, Y. Yamamoto*, Cobalt-Catalyzed Hydroalkylation of [60]Fullerene with Active Alkyl Bromides: Selective Synthesis of Mono-alkylated Fullerenes, J. Am. Chem. Soc. 133(32), 12842–12848, 2011.
[19] S. George, S. Thulasi, S. Anas, K. Radhakrishnan*, Y. Yamamoto, Palladium Catalyzed 1,8-Conjugate Addition to Heptafulvene via Bis-π-allyl Palladium Complexes, Org. Lett. 13(19), 4984–4987, 2011.
[20] T. Jin*, M. Yan, Menggenbateer, T. Minato, M. Bao, Y. Yamamoto*, Nanoporous Copper Metal Catalyst in Click Chemistry: Nanoporosity-Dependent Activity without Supports and Bases, Adv. Synth. Catal. 353(17), 3095–3100, 2011.
[21] F. Yang, T. Jin*, M. Bao, Y. Yamamoto*, Facile Synthesis of Dihaloheterocycles via Electrophilic Iodocyclization, Tetrahedron, 67(52), 10147–10155, 2011.
[22] M. Akhtaruzzaman*, A. Islam, F. Yang, N. Asao, E. Kwon, S. P. Singh, L. Han, Y. Yamamoto*, A Novel Metal-free Panchromatic TiO2 Sensitizer Based on a Phenylenevinyledene-conjugated Unit and an Indoline Derivative for Highly Efficient Dye-sensitized Solar Cells, Chem. Commun. 47(45), 12400–12402, 2011.
[23] T. Kaneko, S. Tanaka, N. Asao*, Y. Yamamoto*, M. Chen, A. Inoue, Reusable and Sustainable Nanostructured Skelton Catalysts: Heck Reaction with Nanoporous Metallic Glass Pd (PdNpore) as a Support, Stabilizer and Ligand Free Catalyst, Adv. Synth. Catal. 353(16), 2927–2932, 2011.
[24] N. Chen, R. Frank, N. Asao, D. Louzguine-Luzgin*, P. Sharma, J. Wang, G. Xie, Y. Ishikawa, N. Hatakeyama, Y. Lin, M. Esashi, Y. Yamamoto, A. Inoue*, Formation and Properties of Au-based Nanograined Metallic Glasses, Acta Materialia 59, 6433–6440, 2011.
[25] H. Aikawa, T. Kaneko, N. Asao*, Y. Yamamoto, Gold-Catalyzed Alkylation of Silyl Enol Ethers with orth-Alkynylbenzoic Acid Esters, Beilstein J. Org. Chem. 7, 648–652, 2011.
[26] S. Tanaka, T. Kaneko, N. Asao*, Y. Yamamoto*, M. Chen, W. Zhang, A. Inoue, A Nanostructured Skelton Catalysts: Suzuki-Coupling with a Reusable and Sustainable Nanoporous Metallic Glass Pd-catalyst, Chem. Commun. 47(21), 5985–5987, 2011.
[27] F. Yang, T. Jin*, M. Bao, Y. Yamamoto*, Facile Synthesis of 3,4-Dihalofuranes via Electrophilic Iodocyclization, Chem. Commun. 47(15), 4541–4543, 2011.
[28] F. Yang, T. Jin*, M. Bao, Y. Yamamoto*, Facile Synthesis of Diiodinated Dihydronaohthalenes and Naphthalenes via Iodine Mediated Electrophilic Cyclization, Chem. Commun. 47(13), 4013–4015, 2011.
[29] F. Yang, T. Jin*, M. Bao, Y. Yamamoto*, Facile Synthesis of 3,4-Diiododihydrothiophenes via Electrophilic Iodocyclization, Tetrahedron Lett. 52(8), 936–938, 2011.
[30] T. Jin*, J. Uchiyama, M. Himuro, Y. Yamamoto*, Triflic Acid-Catalyzed Cascade Cyclization of Arenyl Enynes via Acetylene-Cation Cyclization and Friedel-Crafts Type Reaction, Tetrahedron Lett. 52(17), 2069–2071, 2011.
[31] S. George, J. John, S. Anas, J. John, Y. Yamamoto, E. Suresh, K. V. Radhakrishnan*, Palladium-Catalyzed Bisfunctionalization of Isatylidenes: A Facile Route toward Spiro-Indole-2-ones, Eur. J. Org. Chem. 28, 5489–5497, 2010.
[32] H. Takamura, Y. Yamagami, T. Kishi, S. Kikuchi, Y. Nakamura, I. Kadota*, Y. Yamamoto, Total Synthesis of Brevenal, Tetrahedron 66(29), 5329–5344, 2010. 
[33] N. Asao*, Y. Ishikawa, N. Hatakeyama, Menggenbateer, Y. Yamamoto*, M. Chen, W. Zhang, A. Inoue, Nanostructured Materials as Catalysts: Nanoporous-Gold-Catalyzed Oxidation of Organosilanes with Water, Angew. Chem. Int. Ed. 49(52), 10093–10095, 2010.
[34] T. Jin*, F. Yang, Y. Yamamoto*, Benzannulation from Alkyne without Mrtallic Catalysts at Room Temperature, Org. Lett. 12(2), 388–390, 2010.
[35] Menggenbateer, M. Narsireddy, G. Ferrara, N. Nishina, T. Jin*, Y. Yamamoto*, Gold-catalyzed regiospecific intermolecular hydrothiolation of allenes, Tetrahedron Lett. 51(35), 4627–4629, 2010.
[36] Z. Huo, I. D. Gridnev, Y. Yamamoto*, A Method for the Synthesis of Substituted Quinolines via Electrophilic Cyclization of 1-Azido-2-(2-propynyl)benzene, J. Org. Chem. 75(4), 1266–1270, 2010.
[37] T. Jin*, M. Himuro, Y. Yamamoto*, Br?nsted Acid-Catalyzed Cascade Cycloisomerization of Enynes via Acetylene Cations and sp3-Hybridized C-H Bond Activation, J. Am. Chem. Soc. 132(16), 5590–5591, 2010. 
[38] S. Lu, T. Jin*, M. Bao, Y. Yamamoto*, Palladium-Catalyzed Three-Component [3+2] Cycloaddition of Propargyl Trifluoroacetates, Ethylidene Malonitriles, and Allyltributylstannane, Org. Lett. 12(4), 864–866, 2010.
[39] I. Nakamura*, C. Chan, T. Araki, M. Terada, Y. Yamamoto, Stereochemical Control by an Ester Group or Olefin Ligand in Palladium-Catalyzed Carboalkoxylation of 6-(1-Alkoxyethoxy)hex-2-ynoates, Adv. Synth. Catal. 351(7-8), 1089–1100, 2009.
[40] Z. Huo, T. Kosugi, Y. Yamamoto*, The Direct Formation of 2-Cyano-4-amidopyridine via ?-Cyanation of 4-Amidopyridine N-Oxide with Dimethylcarbamoyl Chloride and Cheap Potassium Cyanide, Acta. Chim. Slov. 56(3), 659–663, 2009.
[41] I. Kadota*, T. Abe, M. Uni, H. Takamura, Y. Yamamoto, Convergent Synthesis of the A-E Ring Segment of Ciguatoxin CTX3C, Tetrahedron, 65(37), 7784–7789, 2009.
[42] Y. Yamamoto*, I. Gridnev, N. Patil, T. Jin, Alkyne Activation with Br?nsted Acids, Iodine, or Gold Complexes, and its Fate Leading to Synthetic Application, Chem. Comm. 34, 5075–5087, 2009. 
[43] T. Jin*, M. Himuro, Y. Yamamoto*, Triflic Acid Catalyzed Synthesis of Spirocycles via Acetylene Cations, Angew. Chem. Int. Ed. 48(32), 5893–5896, 2009.
[44] T. Jin*, F. Yang, C. Liu, Y. Yamamoto*, TfOH-Catalyzed Intramolecular Alkyne-Ketone Metathesis Leading to Highly Substituted Five-membered Cyclic Enones, Chem. Comm. 24, 3533–3535, 2009.
[45] T. Jin*, F. Yang, Y. Yamamoto*, Facile and Efficient Synthesis of Indazole Derivatives by 1,3-Cycloaddition of Arynes with Diazo Compounds and Azomethine Imides, Collect. Czech. Chem. Commun. 74(6), 957–972, 2009. 
[46] H. Takamura, S. Kikuchi, Y. Nakamura, Y. Yamagami, T. Kishi, I. Kadota*, Y. Yamamoto, Total Synthesis of Brevenal, Org. Lett. 11(12), 2531–2534, 2009.
[47] Z. Huo, Y. Yamamoto*, Gold-Catalyzed Synthesis of Isoquinolines via Intramolecular Cyclization of 2-Alkynyl Benzyl Azides, Tetrahedron Lett. 50(26), 3651–3653, 2009.
[48] N. Nishina, Y. Yamamoto*, Gold-Catalyzed Hydrofunctionalization of Allenes with Nitrogen and Oxygen Nucleophiles and its Mechanistic Insights, Tetrahedron 65(9), 1799–1808, 2009.
[49] I. Nakamura*, T. Sato, M. Terada, Y. Yamamoto, Chirality Transfer in Gold-Catalyzed Carbothiolation of o-Alkynylphenyl 1-Arylethyl Sulfides, Org. Lett. 10(13), 2649–2651, 2008.
[50] N. Asao*, S. Yudha S., T. Nogami, Y. Yamamoto, Silver-Catalyzed Synthesis of 1,2-Dihydroisoquinolines Through Direct Addition of Carbon Pronucleophiles to ortho-Alkynylaryl Aldimines, Heterocycles 76(1), 471–483, 2008.
[51] M. Narsireddy, Y. Yamamoto*, Catalytic Asymmetric Intramolecular Hydroamination of Alkynes in the Presence of a Catalytic System Consisting of Pd(0)-Methyl NOrphos (or Tolyl Renorphos)-Benzoic Acid, J. Org. Chem. 73(24), 9698–9709, 2008. 
[52] D. Fischer, H. Tomeba, N. Pahadi, N. Patil, Z. Huo, Y. Yamamoto*, Iodine-Mediated Electrophilic Cyclization of 2-Alkynyl-1-methylene Azide Aromatics Leading to Highly Substituted Isoquinolines and Its Application to the Synthesis of Norchelerythrine, J. Am. Chem. Soc. 130(46), 15720–15725, 2008. 
[53] T. Jin*, F. Kitahara, S. Kamijo, Y. Yamamoto*, Synthesis of 5-Substituted 1H-Tetrazoles by the Copper-Catalyzed [3+2] Cycloaddition of Nitriles and Trimethylsilyl Azides, Chem. Asian J. 3(8-9), 1575–1580, 2008.
[54] N. Patil, Y. Yamamoto*, Coinage Metal-Assisted Synthesis of Heterocycles, Chem. Rev. 108(8), 3395–3442, 2008.
[55] Z. Huo, H. Tomeba, Y. Yamamoto*, Iodine-mediated Electrophilic Cyclization of 2-Alkynylbenzaldoximes leading to the Formation of Iodoisoquinoline N-Oxides, Tetrahedron Lett. 49(38), 5531–5533, 2008.
[56] T. Jin*, Y. Yamamoto*, Gold-Catalyzed Synthesis of Polycyclic Enones from Carbon Tethered 1,3-Enynyl Carbonyls via Tandem Heteroenyne Metathesis and Nazarov Reaction, Org. Lett. 10(14), 3137–3139, 2008.
[57] N. Nishina, Y. Yamamoto*, Gold-Catalyzed Intermolecular Hydroalkoxylation of Allenes: Difference in Mechanism between Hydroalkoxylation and Hydroamination, Tetrahedron Lett. 49(33), 4908–4911, 2008.
[58] Z. Huo, T. Kosugi, Y. Yamamoto*, Zinc Cyanide Mediated Direct α-Cyanation of Isonicotinic Acid N-Oxide. Application to the Synthesis of FYX-051, a Xanthine Oxidoreductase Inhibitor, Tetrahedron Lett. 49(28), 4369–4371, 2008.
[59] S. Lu, Z. Xu, M. Bao*, Y. Yamamoto*, Carbocycle Synthesis through Facile and Efficient Palladium-Catalyzed Allylative Dearomatization of Naphthalene and Phenanthrene Allyl Chlorides, Angew. Chem. Int. Ed. 47(23), 4366–4369, 2008.
[60] I. Kadota*, T. Abe, M. Uni, H. Takamura, Y. Yamamoto, A Cross-Metathesis Approach to the Stereocontrolled Synthesis of the AB Ring Segment of Ciguatoxin, Tetrahedron Lett. 49(22), 3643–3647, 2008.
[61] T. Jin, F. Kitahara, S. Kamijo, Y. Yamamoto*, Copper-Catalyzed Synthesis of 5-Substituted 1H-Tetrazoles via the [3+2] Cycloaddition of Nitriles and Trimethylsilyl Azide, Tetrahedron Lett. 49(17), 2824–2827, 2008.
[62] I. Nakamura*, C. Chan, T. Araki, M. Terada, Y. Yamamoto, Synthesis of Multisubstituted 2-(Dihydrofuran-2(3H)-ylidene)acetates via Intramolecular Carboalkoxylation by Platinum-Olefin Catalyst System, Org. Lett. 10(2), 309–312, 2008.
[63] I. Nakamura*, U. Yamagishi, D. Song, S. Konta, Y. Yamamoto, Synthesis of 3- and 6-Sulfonylindoles from ortho-Alkynyl-N-sulfonylanilines by the Use of Lewis Acidic Transition-Metal Catalysts, Chem. Asian. J. 3(2), 285–295, 2008.

 
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